磷氯铅矿和砷铅矿的原位高压单晶X射线衍射研究

doi:10.11889/j.0253-3219.2019.hjs.42.020101

Nuclear Science and Techniques ›› 2019, Vol. 42 ›› Issue (2): 20101-020101.doi: 10.11889/j.0253-3219.2019.hjs.42.020101

In-situ high-pressure single crystal X-ray diffraction of natural pyromorphite and mimetite

Xi CHEN¹,Xun XU¹,Fei QIN²,Yingxin LIU¹()

1. School of Gemmology, China University of Geosciences, Beijing 100083, China
2. School of Earth and Space Sciences, Peking University, Beijing 100871, China

Received:2018-09-06 Revised:2018-11-16 Online:2019-02-10 Published:2019-02-19
Contact: Yingxin LIU E-mail:liuyingxin@cugb.edu.cn
About author:CHEN Xi, female, born in 1995, graduated from Institute of Disaster Prevention Science and Technology in 2016, master student, focusing on gemology|CHEN Xi, female, born in 1995, graduated from Institute of Disaster Prevention Science and Technology in 2016, master student, focusing on gemology|LIU Yingxin, E-mail:<email>liuyingxin@cugb.edu.cn</email>
Supported by:
Supported by National Natural Science Foundation of China (No.41202027), the Fundamental Research Funds for the Central Universities (No.2652017090)

磷氯铅矿Pyromorphite								砷铅矿Mimetite
氧化物 Compound	质量百分比 / %	元素 Element	质量百分比 / %	氧化物 Compound	质量百分比 / %	元素 Element	质量百分比 / %	氧化物 Compound	质量百分比 / %	元素 Element	质量百分比 / %
PbO	78.73	Pb	73.09	SrO	0.014 1	Sr	0.011 9	PbO	74.2	Pb	68.876 0
P₂O₅	8.89	Px	3.88	Br	0.011 7	Br	0.011 7	As₂O₃	21.3	As	16.136 0
SiO₂	5.46	Si	2.55	Yb₂O₃	0.010 2	Yb	0.009	Cl	2.13	Cl	2.129 9
Cl	1.68	Cl	1.68	MoO₃	0.017 6	Mo	0.011 7	CaO	0.524	Ca	0.374 3
Al₂O₃	1.20	Al	0.636	Am₂O₃	0.015	Am	0.014	P₂O₅	0.516	P	0.255 2
OsO₄	0.469	Os	0.315	Dy₂O₃	0.014 4	Dy	0.012 5	SiO₂	0.209	Si	0.097 5
Fe₂O₃	0.365	Fe	0.255	SnO₂	0.009 4	Sn	0.074	Al₂O₃	0.102	Al	0.053 4
CaO	0.326	Ca	0.233	Pr₆O₁₁	0.007 1	Pr	0.005 9	F	0.074 6	F	0.074 8
MgO	0.314	Mg	0.189	ZrO₂	0.007	Zr	0.005	Fe₂O₃	0.071 5	Fe	0.050 0
Na₂O	0.277	Na	0.205	In₂O₃	0.006 4	In	0.005 3	ReO₂	0.024 3	Re	0.020 7
K₂O	0.104	K	0.086 3	NiO	0.005	Ni	0.003 9	NiO	0.018 5	Ni	0.014 5
As₂O₃	0.085	As	0.065	ZnO	0.004 9	Zn	0.003 9	Na₂O	0.007	Na	0.005 2
La₂O₃	0.072	La	0.061	Ta₂O₅	0.003 7	Ta	0.003
U₃O₈	0.069 1	U	0.058 6	GeO₂	0.002 7	Ge	0.001 9
TiO₂	0.063 0	Ti	0.037 9	Cr₂O₃	0.002 5	Cr	0.001 7
Bi₂O₃	0.053 4	Bi	0.047 9	BaO	0.002	Ba	0.002
HgO	0.039 3	Hg	0.036 4	I	0.001 4	I	0.001 4
HfO₂	0.027 1	Hf	0.023	SeO₂	0.000 1	Se	0.000 1
Rb₂O	0.023 1	Rb	0.021 1
合计Total	98.247		83.470 2		0.135 2		0.178 9	合计Total	99.176 9		88.087 5

压力 Pressure / GPa	磷氯铅矿Pyromorphite			砷铅矿Mimetite
压力 Pressure / GPa	a / nm	c / nm	V / nm³	a / nm	c / nm	V / nm³
0.000 1	0.998 1(3)	0.734 0(4)	0.638 4(3)	1.023 9(2)	0.743 2(2)	0.672 1(2)
1.93(4)	0.990 3(1)	0.728 5(3)	0.618 7(2)	1.017 5(1)	0.737 6(1)	0.661 4(1)
2.19(5)	0.989 0(1)	0.726 0(3)	0.615 1(1)	1.016 4(1)	0.737 0(1)	0.659 3(1)
2.95(6)	0.985 7(1)	0.724 0(3)	0.609 2(2)	1.012 6(1)	0.735 0(2)	0.652 7(2)
3.79(1)	0.981 3(1)	0.722 8(3)	0.602 9(2)	1.009 2(1)	0.731 8(2)	0.645 4(1)
4.19(3)	0.980 4(1)	0.721 3(3)	0.600 9(2)	1.007 4(1)	0.730 8(1)	0.642 2(2)
4.94(4)	0.977 9(1)	0.719 9(3)	0.595 6(2)	1.004 3(1)	0.728 6(2)	0.636 4(2)
5.47(6)	0.976 6(1)	0.716 7(3)	0.592 1(2)	1.001 7(1)	0.727 5(1)	0.632 1(3)
6.24(8)	0.973 6(2)	0.714 8(3)	0.587 0(2)	0.998 9(2)	0.725 7(1)	0.627 0(2)
6.85(2)	0.971 6(1)	0.714 0(3)	0.583 8(2)	0.997 0(1)	0.724 6(1)	0.623 8(2)
7.68(6)	0.968 8(1)	0.712 4(3)	0.579 1(2)	0.994 1(1)	0.722 7(1)	0.618 6(1)
8.18(7)	0.967 3(1)	0.711 5(3)	0.576 5(2)	0.992 5(2)	0.721 2(2)	0.615 3(2)
8.85(8)	0.965 2(1)	0.710 4(3)	0.573 2(1)	0.991 4(2)	0.719 3(1)	0.612 2(2)
9.39(8)	0.963 2(1)	0.709 8(3)	0.570 3(2)	0.988 0(1)	0.718 4(1)	0.608 4(3)
9.90(8)	0.962 0(1)	0.708 6(2)	0.567 3(1)	0.987 1(1)	0.715 2(2)	0.603 5(1)
10.74(15)	0.960 7(1)	0.707 4(3)	0.565 9(2)	0.984 9(3)	0.713 5(1)	0.600 0(3)
11.51(12)	0.958 5(2)	0.707 0(2)	0.563 1(1)	0.983 5(2)	0.713 0(1)	0.597 2(2)

矿物 Mineral	体积模量 K ₀/ GPa	体积模量导数 K ₀'	压力范围 Pressure range / GPa	实验方法 Methods	数据来源 Data sources
Pb₅(PO₄)₃Cl	52.3(17)	8.9(6)	0~11.51	单晶Single crystal	本实验This experiment
	67.7(17)	4(fixed)	0~11.51	单晶Single crystal	本实验This experiment
	44(6)	15(3)	0~14.1	粉晶Powder	Wei et al. 2013
	78(4)	4(fixed)	0~14.1	粉晶Powder	Wei et al. 2013
Pb₅(AsO₄)₃Cl	87.4(39)	1.2(6)	0~11.51	单晶Single crystal	本实验This experiment
	74.9(19)	4(fixed)	0~11.51	单晶Single crystal	本实验This experiment
	46(8)	15(4)	0~14.1	粉晶Powder	Wei et al. 2013
	83(5)	4(fixed)	0~14.1	粉晶Powder	Wei et al. 2013
Pb₅(VO₄)₃Cl	41(5)	12.5(2.5)	0~7.7	粉晶Powder	Gatta et al. 2009
	57(1)	4(fixed)	0~7.7	粉晶Powder	Gatta et al. 2009
	55(1)	6.1(5)	0~8.74	粉晶Powder	Fan et al. 2013
	63(1)	4(fixed)	0~8.74	粉晶Powder	Fan et al. 2013

1	刘羽, 彭明生 . 磷灰石结构替换的研究进展[J]. 岩石矿物学杂志, 2004, 22(4): 413-415. DOI: 10.3969/j.issn.1000-6524.2003.z1.021. doi: 10.3969/j.issn.1000-6524.2003.z1.021.
	LIU Yu , PENG Mingsheng . Advances in researches on structural substitution of apatite[J]. Acta Petrologica Et Mineralogica, 2004, 22(4): 413-415. DOI: 10.3969/j.issn.1000-6524.2003.z1.021. doi: 10.3969/j.issn.1000-6524.2003.z1.021.
2	刘羽, 胥焕岩 . 磷灰石结构通道离子对晶胞参数的影响[J]. 矿物岩石, 2004, 21(1): 1-4. DOI: 10.3969/j.issn.1001-6872.2001.01.001. doi: 10.3969/j.issn.1001-6872.2001.01.001.
	LIU Yu , XU Huanyan . The effects of structural channel inos of apatite on their lattice parameters[J]. Journal of Mineralogy and Petrology, 2004, 21(1): 1-4. DOI: 10.3969/j.issn.1001-6872.2001.01.001. doi: 10.3969/j.issn.1001-6872.2001.01.001.
3	Murayama J K , Nakai S , Kato M , et al . A dense polymorph of Ca₃(PO₄)₂: a high pressure phase of apatite decomposition and its geochemical significance[J]. Physics of the Earth & Planetary Interiors, 1986, 44(4): 293-303. DOI: 10.1016/0031-9201(86)90057-9. doi: 10.1016/0031-9201(86)90057-9.
4	Beswick A E , Carmichael I S E . Constraints on mantle source compositions imposed by phosphorus and the rare-earth elements[J]. Contributions to Mineralogy & Petrology, 1978, 67(3): 317-330. DOI: 10.1007/BF00381459. doi: 10.1007/BF00381459.
5	Brunet F , Allan D R , Redfern S A T , et al . Compressibility and thermal expansivity of synthetic apatites, Ca₅(PO₄)₃X with X=OH, F and Cl[J]. European Journal of Mineralogy, 1999, 11(6): 1023-1035.
6	Matsukage K N , Ono S , Kawamoto T , et al . The compressibility of a natural apatite[J]. Physics & Chemistry of Minerals, 2012, 31(9): 580-584. DOI: 10.1007/s00269-004-0415-x. doi: 10.1007/s00269-004-0415-x.
7	Hiroki O . Relationships among channel topology and atomic displacements in the structures of Pb₅(BO₄)₃Cl with B=P (pyromorphite), V (vanadinite), and As (mimetite)[J]. American Mineralogist, 2013, 98(8-9): 1573-1579. DOI: 10.2138/am.2013.4417. doi: 10.2138/am.2013.4417.
8	Antao S M , Dhaliwal I . Lead apatites: structural variations among Pb₅(BO₄)₃Cl with B=P (pyromorphite), As (mimetite) and V (vanadinite)[J]. Journal of Synchrotron Radiation, 2018, 25(1): 214-221. DOI: 10.1107/S1600577517014217. doi: 10.1107/S1600577517014217.
9	Gatta G D , Lee Y , Kao C C . Elastic behavior of vanadinite, Pb₁₀(VO₄)₆Cl₂, a microporous non-zeolitic mineral[J]. Physics & Chemistry of Minerals, 2008, 36(6): 311-317. DOI: 10.1007/s00269-008-0279-6. doi: 10.1007/s00269-008-0279-6.
10	Wei S Y , Ma M N , Fan D W , et al . Compressibility of mimetite and pyromorphite at high pressure[J]. High Pressure Research, 2013, 33(1): 27-34. DOI: 10.1080/08957959.2013.765003. doi: 10.1080/08957959.2013.765003.
11	Fan D W , Ma M N , Wei S Y , et al . In-situ synchrotron powder X-ray diffraction study of vanadinite at room temperature and high pressure[J]. High Temperatures- High Pressures, 2013, 42(5): 441-449.
12	Dai Y , Hughes J M . Crystal-structure refinements of vanadinite and pyromorphite[J]. Canadian Mineralogist, 1989, 27(7): 189-192.
13	Hashimoto H , Matsumoto T . Structure refinements of two natural pyromorphites, Pb₅(PO₄)₃Cl, and crystal chemistry of chlorapatite group, M₅(PO₄)₃Cl[J]. Zeitschrift Für Kristallographie, 1998, 213(11): 585-590. DOI: 10.1524/zkri.1998.213.11.585. doi: 10.1524/zkri.1998.213.11.585.
14	郑海飞, 孙樯, 赵金, 等 . 金刚石压腔高温高压实验的压力标定方法及其现状[J]. 高压物理学报, 2004, 18(1): 78-82. DOI: 10.3969/j.issn.1000-5773.2004.01.014. doi: 10.3969/j.issn.1000-5773.2004.01.014.
	ZHENG Haifei , SUN Qiang , ZHAO Jin , et al . Comment on the gauge for the experiments at high temperature and high pressure with DAC[J]. Chinese Journal of High Pressure Physics, 2004, 18(1): 78-82. DOI: 10.3969/j.issn.1000-5773.2004.01.014. doi: 10.3969/j.issn.1000-5773.2004.01.014.
15	Dera P , Zhuravlev K , Prakapenka V , et al . High pressure single-crystal micro X-ray diffraction analysis with GSE_ADA/RSV software[J]. High Pressure Research, 2013, 33(3): 466-484. DOI: 10.1080/08957959.2013. 806504. doi: 10.1080/08957959.2013. 806504.
16	Holland T , Sat R . Unit cell refinement from powder diffraction data: the use of regression diagnostics[J]. Mineralogical Magazine, 1997, 61(404): 65-77. DOI: 10.1180/minmag.1997.061.404.07. doi: 10.1180/minmag.1997.061.404.07.
17	Flis J , Borkiewicz O , Bajda T , et al . Synchrotron-based X-ray diffraction of the lead apatite series Pb₁₀(PO₄)₆Cl₂- Pb₁₀(AsO₄)₆Cl₂ [J]. Journal of Synchrotron Radiation, 2010, 17(2): 207-214. DOI: 10.1107/S0909049509048705. doi: 10.1107/S0909049509048705.
18	Liu X , Shieh S R , Fleet M E , et al . High-pressure study on lead fluorapatite[J]. American Mineralogist, 2008, 93(10): 1581-1584. DOI: 10.2138/am.2008.2816. doi: 10.2138/am.2008.2816.

[1]	Dandan JIA,Min ZHANG,Yongjun LI,Shuai WU,Limin JIN,Song XUE. Design of the super-small angle Canted front-end at SSRF [J]. Nuclear Techniques, 2019, 42(9): 0-090101-6.
[2]	Qigang WU,Sumei LIU,Mingzhun LEI,Kun XU,Wei HUANG. Thermal analysis of CFETR blanket back supporting structure and channels under multiple operating conditions [J]. Nuclear Techniques, 2019, 42(9): 0-090602-8.
[3]	Huiqing LIN Liangcheng CAI Maoyuan HUANG Chaochao ZHANG Xiaochun FU Yuan FAN. Stress analysis and structural analysis and optimization of high temperature molten salt pump in TMSR-SF0 based on ANSYS [J]. Nuclear Techniques, 2019, 42(9): 0-090604-7.
[4]	Yongxiang HUA, Peirong GONG. Application of Laplace enhancement in spot position measurement offluorescent screen imaging [J]. Nuclear Techniques, 2019, 42(8): 80101-080101.
[5]	Hanjie CAO,Hongliang BAO,Haisheng YU,Yuying HUANG,Jianqiang WANG. Lattice modification of U₃O₈ matrix induced by cerium substitution [J]. Nuclear Techniques, 2019, 42(7): 0-070101-7.
[6]	Qingyuan LI,Bo XU,Chong ZHOU,Yang ZOU,Hongjie XU. The optimization of flow rate distribution design of 373 MW molten salt reactor-liquid fuel [J]. Nuclear Techniques, 2019, 42(7): 0-070605-10.
[7]	Xuemin WU, Yong ZHANG, Meisheng HE, Jieqiong JIANG. Study on sloshing response characteristics of liquid heavy metal coolant [J]. Nuclear Science and Techniques, 2019, 42(4): 40603-040603.
[8]	Jiaqi CHEN, Runze QI, Yufei FENG, Qiushi HUANG, Zhanshan WANG. Au-Pt coatings for synchrotron radiation applications [J]. Nuclear Science and Techniques, 2019, 42(3): 30101-030101.
[9]	Lubei LIU, Chunlong LI, Peiyan YU, Fengfeng WANG, Chenzhang YUAN, Yuan HE, Shenghu ZHANG, Bin ZHANG. Development of RF superconducting cavity forward power coupler [J]. Nuclear Science and Techniques, 2019, 42(2): 20201-020201.
[10]	GAO Bo, LENG Yongbin, CHEN Hanjiao, CHEN Jie. Slit separation rapid scanning system for synchrotron radiation interferometer [J]. Nuclear Techniques, 2018, 41(8): 80101-080101.
[11]	JIN Xin, WANG Jianjun, LI Yiwen, HUANG Da, YANG Chunming, BIAN Fenggang, WANG Jie. In-situ SAXS study on self-assembly of copolymer PS-b-PAA [J]. Nuclear Techniques, 2018, 41(8): 80102-080102.
[12]	LI Zhiyao, CHEN Han, DU Yingchao. Nonlinear compensation in velocity realized by wakefield structure [J]. Nuclear Techniques, 2018, 41(8): 80202-080202.
[13]	JIN Limin, SONG Li, ZHU Wanqian, LUO Hongxin, XU Zhongmin, ZHANG Zengyan. Positioning and characterization of micro-damage on silicon crystal surface based on optical interference method [J]. Nuclear Techniques, 2018, 41(7): 70101-070101.
[14]	XIE Chunyu, CAO Hanjie, YUE Zenghui, BAO Hongliang, WANG Jianqiang. Study on the microstructure of Th_1-xU_xO_2+y by synchrotron radiation XAFS technique [J]. Nuclear Techniques, 2018, 41(7): 70102-070102.
[15]	MIAO Hongkang, CHEN Yushuang, LYU Liushuai, WANG Xiao, XU Guangdi, WANG Naxiu. Flow-induced vibration analysis of heat transfer tube based on two-way fluid-structure interaction [J]. Nuclear Techniques, 2018, 41(5): 50602-050602.

In-situ high-pressure single crystal X-ray diffraction of natural pyromorphite and mimetite

RichHTML

PDF (PC)

Like

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 9

References 18

Related Articles 15

Metrics

Comments

Recommended 10