甲基丙烯酸酯类含硅有机单体的制备及其光固化

doi:10.11889/j.1000-3436.2017.rrj.35.030302

Journal of Radiation Research and Radiation Proces ›› 2017, Vol. 35 ›› Issue (3): 30302-030302.doi: 10.11889/j.1000-3436.2017.rrj.35.030302

• RADIATION CHEMISTRY • Previous Articles Next Articles

Preparation and UV curing of silicon-containing methyl methacrylate monomer

GUO Xiuping, LI Jie, YU Liujian, WANG Yong, WANG Tao

College of Science, Beijing University of Chemical Technology, Beijing 100029, China

Received:2017-03-14 Revised:2017-04-13 Online:2017-06-20 Published:2017-06-15

Abstract

Abstract:

A poly-functional silicon-containing acrylate monomer, MAE-Si-OCH₃, was synthesized via transesterification reaction using γ-(meth-acryloxypropyl) trimethoxy silane and hydroxyethyl methylacrylate as raw materials and sodium ethoxide as the catalyst. The structure of MAE-Si-OCH₃ was characterized by Fourier transform infrared (FTIR) spectroscopy and ¹H-NMR. The ratio of double bond and methoxy groups in the monomer was determined by ¹H-NMR. The photopolymerization reaction of MAE-Si-OCH₃ was also studied, and its resistance to acids, alkalis, and hardness were tested. The results show that MAE-Si-OCH₃ displays excellent photopolymerization efficiency, has a good resistance towards acids and alkalis and is quite hard.

Key words: Poly-functional monomer, UV-curable, Free radical

CLC Number:

TL13

GUO Xiuping, LI Jie, YU Liujian, WANG Yong, WANG Tao. Preparation and UV curing of silicon-containing methyl methacrylate monomer[J].Journal of Radiation Research and Radiation Proces, 2017, 35(3): 30302-030302.

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Preparation and UV curing of silicon-containing methyl methacrylate monomer

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