氢化丁腈橡胶的辐射硫化及其性能研究

doi:10.11889/j.1000-3436.2019.rrj.37.010201

Journal of Radiation Research and Radiation Processing ›› 2019, Vol. 37 ›› Issue (1): 10201-010201.doi: 10.11889/j.1000-3436.2019.rrj.37.010201

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Radiation vulcanization and properties of hydrogenated butadiene-acrylonitrile rubber

CHENG Anren¹(),DAI Pei¹(),YANG Hongjun²,YUAN Ke³,JIAO Yang¹(),LU Yongjun¹,WANG Liancai¹,BAO Mao¹

1. Beijing Research Center for Radiation Application, Beijing 100015, China
2. Troop 63963, Beijing 100072, China
3. Inner Mongolia First Machinery Group Corporation, Baotou 014032, China

Received:2018-09-30 Revised:2018-11-16 Accepted:2018-11-16 Online:2019-02-20 Published:2019-01-30
Contact: Yang JIAO E-mail:rubbertire@163.com;jiaoyang7171@sina.com
About author:>CHENG Anren was born in October 1972, and received his bachelor’s degree from Hubei University of Technology in 1997. Now he is a senior engineer at Beijing Research Center of Radiation Application, majoring in radiation modification and application of polymer materials. E-mail: rubbertire@163.com|DAI Pei was born in July 1987, and received his doctoral degree from Beijing University of Chemical Technology in 2016. Now he is a post doctor at Beijing Research Center of Radiation Application, majoring in radiation preparation and properties of functional materials. E-mail: daipei008@126.com|JIAO Yang, associate professor, E-mail:jiaoyang7171@sina.com
Supported by:
National Natural Science Foundation of China (11805016), China Postdoctoral Science Foundation (2018M631377), and Building of Innovative Team Plan (IG201703N)

原材料 Raw material	A	B	C
HNBR3446	100	100	100
ZnO	?	4	4
硬脂酸 SA	?	1	1
微晶蜡Microcrystalline wax	1.5	1.5	1.5
防老剂4020 Antiager 4020	1.5	1.5	1.5
防老剂RD Antiager RD	1	1	1
C5树脂 Resin C5	3	3	3
碳黑 Carbon black	75	75	75
硫磺粉 Sulphur	?	0.25	0.5
促进剂 Promoter	?	1.5	3
其它 Others	?	1.25	2.5
合计 In total	182	190	193

实验编号Sample number	A150	A200	A250	A300
硬度(邵A) Shore A hardness / 度	79	81	83	84
100%定伸应力 Tensile strength at 100% / MPa	8.74	10.72	12.68	14.38
拉伸强度 Tensile strength / MPa	15.04	17.09	17.3	18.87
扯断伸长率 Elongation at break / %	249	202.5	171.28	168.05
浸泡后体积变化率Volume change rate / %	26.34	23.77	22.55	22.41

试样编号 Sample number		A250	B100	C0
硫化条件 Vulcanization condition⁽¹⁾		－	170 ^oC×10 min	170^oC × 10 min +150^oC × 4 h
初始性能 Initial properties	硬度(邵A) Shore A hardness / 度	83	83	83
	100%定伸应力Tensile strength at 100% / MPa	12.68	10.53	8.64
	拉伸强度Tensile strength / MPa	17.30	17.34	17.74
	扯断伸长率Elongation at break / %	171	284	290
热空气老化后⁽²⁾ Hot air ageing	硬度(邵A) / 度 Shore A hardness	+1	+4	+5
	100%定伸应力保持率 / % Retention rate of tensile strength at 100%	123.3	137.8	166.1
	拉伸强度保持率 / % Retention rate of tensile strength	130.6	121.2	106.7
	扯断伸长率保持率 / % Retention rate of elongation at break	89.0	65.5	49.7
高温油浸泡后⁽³⁾ Hot oil ageing	硬度(邵A) Shore A hardness / 度	?15	?18	?19
	100%定伸应力保持率Retention rate of tensile strength at 100% / %	69.4	66.2	63.8
	拉伸强度保持率Retention rate of tensile strength / %	95.6	102.4	97.7
	扯断伸长率保持率Retention rate of elongation at break / %	133.2	135.6	131.3
	体积变化率Volume change rate / %	22.55	24.46	25.98
	压缩永久变形Compression set / %	46.20	56.78	58.56

1	Pan L , Tan J Z , Han X M , et al . Effects of elevated temperature and crude oil on the properties of a hydrogenated nitrile butadiene rubber elastomer[J]. Journal of Applied Polymer Science, 2016, 133(40): 44012. DOI: 10.1002/app.44012. doi: 10.1002/app.44012.
2	Wang G Z , Wang Z L , Tian S C , et al . Morphology evolution and mechanical properties of HNBR composites reinforced by HZMMA/carbon black during curing process[J]. Applied Mechanics and Materials, 2015, 740: 23-27. DOI: 10.4028/www.scientific.net/AMM.740.23. doi: 10.4028/www.scientific.net/AMM.740.23.
3	Cao P , Su N , Li C , et al . Highly active and reusable rhodium catalyst for selective hydrogenation of nitrile-butadiene rubber[J]. Rubber Chemistry and Technology, 2015, 88(4): 547-559. DOI: 10.5254/rct.15.84894. doi: 10.5254/rct.15.84894.
4	梁滔 . 氢化丁腈橡胶的加工技术与应用进展[J]. 合成橡胶工业, 2017, 40(2): 158-163. DOI: 10.3969/j.issn.1000-1255.2017.02.018. doi: 10.3969/j.issn.1000-1255.2017.02.018.
	LIANG Tao . Advances of processing technology and application of hydrogenated nitrile rubber[J]. China Synthetic Rubber Industry, 2017, 40(2): 158-163. DOI: 10.3969/j.issn.1000-1255.2017.02.018. doi: 10.3969/j.issn.1000-1255.2017.02.018.
5	Guo J H , Chen X M , Li Z C . Thermal oil aging behavior of hydrogenated nitrile butadiene rubber/multi-walled carbon nanotube composites under free or compression state[J]. Journal of Elastomers and Plastics, 2017, 50(5): 448-462. DOI: 10.1177/0095244317731950. doi: 10.1177/0095244317731950.
6	Norris C J , Hale M , Bennett M . Composition and property changes of HNBR and FKM elastomers after sour gas aging[J]. Plastics, Rubber and Composites, 2016, 45(6): 239-246. DOI: 10.1080/14658011.2016. 1177271. doi: 10.1080/14658011.2016. 1177271.
7	Gu Z , Song G J , Liu W S , et al . Structure and properties of hydrogenated nitrile rubber/organo-montmorillonite nanocomposites[J]. Clays and Clay Minerals, 2010, 58(1): 72-78. DOI: 10.1346/CCMN.2010.0580107. doi: 10.1346/CCMN.2010.0580107.
8	Sanprasert P , Sombatsompop N , Sae-Oui P , et al . Cotton fibers reinforcement of hnbr: control of fiber alignment and its influence on properties of HNBR vulcanizates[J]. Journal of Applied Polymer Science, 2015, 131(22): 547-557. DOI: 10.1002/app.41090. doi: 10.1002/app.41090.
9	Psarras G C , Sofos G A , Vradis A , et al . HNBR and its MWCNT reinforced nanocomposites: Crystalline morphology and electrical response[J]. European Polymer Journal, 2014, 54(1): 190-199. DOI: 10.1016/j.eurpolymj.2014.03.002. doi: 10.1016/j.eurpolymj.2014.03.002.
10	Ma H L , Zhang L , Zhang Y W , et al . Radiation preparation of graphene/carbon nanotubes hybrid fillers for mechanical reinforcement of poly(vinyl alcohol) films[J]. Radiation Physics and Chemistry, 2016, 118: 21-26. DOI: 10.1016/j.radphyschem.2015.03.028. doi: 10.1016/j.radphyschem.2015.03.028.
11	Wang W Z , Wang L C , Jiao Y , et al . Fine dispersion morphology of polystyrene/poly(ethylene terephthalate glycol) blending generation for controlled foaming behavior[J]. RSC Advances, 2017, 7(62): 39138-39146. DOI: 10.1039/C7RA07297J. doi: 10.1039/C7RA07297J.
12	Yu H Y , Yan J , Ma H L , et al . Creating poly(ethylene glycol) film on the surface of niti alloy by gamma irradiation[J]. Radiation Physics and Chemistry, 2015, 112: 199-202. DOI: 10.1016/j.radphyschem.2015.03.004. doi: 10.1016/j.radphyschem.2015.03.004.
13	杨明成, 朱军 . 高分子材料辐射加工技术及应用[M]. 郑州: 郑州大学出版社, 2010: 135-138.
	YANG Mingcheng , ZHU Jun . Polymer materials radiation processing technology and application[M]. Zhengzhou: Zhengzhou University Press, 2010: 135-138.
14	翟茂林, 伊敏, 哈鸿飞 . 高分子材料辐射加工技术及进展[M]. 北京: 化学工业出版社, 2004: 81-90.
	ZHAI Maolin , YI Min , Hongfei HA . Polymer materials radiation processing technology and progress[M]. Beijing: Chemical Industry Press, 2004: 81-90.
15	Dai P , Cheng A R , Zhao X M , et al . Fabrication and mechanical properties of γ-ray radiation vulcanized hnbr with high recovery after compression[J]. Radiation Physics and Chemistry, 2018, 151: 271-275. DOI: 10.1016/j.radphyschem.2018.03.012. doi: 10.1016/j.radphyschem.2018.03.012.
16	哈鸿飞, 吴季兰 . 高分子辐射化学:原理与应用[M]. 北京: 北京大学出版社, 2003: 79-83.
	Hongfei HA , WU Jilan . Radiation chemistry of polymer: principle and application[M]. Beijing: Peking University Press, 2003: 79-83.
17	何平笙 . 新编高聚物的结构与性能[M]. 北京: 科学出版社, 2009: 21-23.
	HE Pingsheng . The structure and properties of polymer[M]. Beijing: Science Press, 2009: 21-23.
18	Zhao W , Yu L , Zhong X , et al . Radiation vulcanization of hydrogenated acrylonitrile butadiene rubber (HNBR)[J]. Journal of Applied Polymer Science, 1994, 54: 1199-1205. DOI: 10.1002/app.1994.070540902. doi: 10.1002/app.1994.070540902.
19	梁星宇, 周木英 . 橡胶工业手册[M]. 北京: 化学工业出版社, 1992: 229-231.
	LIANG Xingyu , ZHOU Muying . Rubber industry handbook[M]. Beijing: Chemical Industry Press, 1992: 229-231.
20	杨清芝 . 现代橡胶工艺学[M]. 北京: 中国石化出版社, 2004: 387-389.
	YANG Qingzhi . Modern rubber technology[M]. Beijing: China Petrochemical Press, 2004: 387-389.
21	胡国文, 刘碧, 杜纪富, 等 . 辐射硫化对三元乙丙橡胶力学性能的影响[J]. 辐射研究与辐射工艺学报, 2012, 30(2): 81-86.
	HU Guowen , LIU Bi , DU Jifu , et al . Effect of radiation vulcanization on the mechanical properties of ethylene propylene dine terpolymer rubber[J]. Journal of Radiation Research and Radiation Processing, 2012, 30(2): 81-86.
22	程安仁, 张艳霞, 汪文昭, 等 . 天然橡胶辐射预硫化技术的应用研究[J]. 特种橡胶制品, 2016, 37: 45-48.
	CHENG Anren , ZHANG Yanxia , WANG Wenzhao , et al . Application research of radiation pre-curing technology of NR[J]. Special Purpose Rubber Products, 2016, 37: 45-48.
23	何小海, 董毛华, 谢春梅 . 电子束辐射交联的原理及应用[J]. 轮胎工业, 2010, 30: 42-45.
	HE Xiaohai , DONG Maohua , XIE Chunmei . Principle and application of electron beam radiation vulcanization[J]. Tire Industry, 2010, 30: 42-45.

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Radiation vulcanization and properties of hydrogenated butadiene-acrylonitrile rubber

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