Journal of Radiation Research and Radiation Proces ›› 2017, Vol. 35 ›› Issue (4): 40301-040301.doi: 10.11889/j.1000-3436.2017.rrj.35.040301

• RADIATION CHEMISTRY • Previous Articles     Next Articles

Radiation synthesis of lithium-ion-response hydrogels based on crown ether

LIU Siqi, CAO Pengfei, PENG Jing, LI Jiuqiang, ZHAI Maolin   

  1. Beijing National Laboratory for Molecular Sciences, Radiochemistry and Radiation Chemistry Key Laboratory of Fundamental Science, the Key Laboratory of Polymer Chemistry and Physics of Ministry of Education, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China
  • Received:2017-03-23 Revised:2017-04-27 Online:2017-08-20 Published:2017-07-29
  • Supported by:

    Supported by National Natural Science Foundation of China (U1430234)

Abstract:

A novel poly-(acrylamide-co-vinyl-12-crown-4-ether) (PAM-12C4) hydrogel with a specific lithium- ion-response was synthesized via radiation-induced copolymerization and cross linking. The resultant PAM-12C4 was characterized by gel fraction, micro-FTIR spectroscopy, and thermo gravimetric analysis (TGA). The swelling behavior of PAM-12C4 in a lithium salt solution was also studied. The results showed that the PAM-12C4 hydrogel was successfully synthesized with a gel fraction of 94% at a dose of 10 kGy. The resultant PAM-12C4 hydrogel exhibits good thermal stability and gives an obvious response to the lithium-ion in an aqueous solution.

Key words: Radiation copolymerization, Crown ether hydrogels, Lithium, Ion-response

CLC Number: 

  • TL13