Journal of Radiation Research and Radiation Proces ›› 2014, Vol. 32 ›› Issue (5): 9-050303.doi: 10.11889/j.1000-3436.2014.rrj.32.050303

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Study on radiation modification of ionic liquid/poly(vinylidene fluoride) electrolyte film

DONG Zhen1,2,3  PENG Jing2  ZHANG Xing2  LI Jiuqiang2  JU Xuecheng1  ZHAI Maolin1,2  ZHAO Long3   

  1. 1(Peking University Shenzhen Institute, Shenzhen 518057, China)
    2 (Beijing National Laboratory for Molecular Sciences, Key Laboratory of Polymer Chemistry and Physics of Ministry of Education, Radiochemistry & Radiation Chemistry Key Laboratory for Foundamental Science, College of Chemistry & Molecular Engineering, Peking University, Beijing 100871, China)
    3 (Hubei Collaborative Innovation Center of Non-power Nuclear Technology, Hubei University of Science and Technology,
    Xianning 437100, China)
  • Received:2014-05-06 Revised:2014-06-12 Online:2014-10-20 Published:2014-09-15

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Abstract:

Radiation modification of the AVImCl/PVDF electrolyte films prepared via casting the mixture of ionic liquid containing unsaturated double bond 1-allyl-3-vinyl imidazole chloride (AVImCl) and poly(vinylidene fluoride) (PVDF) was investigated. The properties of AVImCl/PVDF electrolyte films were characterized by SEM, TG, DSC as well as ionic conductivity and mechanical test. The results showed that AVImCl was polymerized or grafted on PVDF chains under irradiation, contributing to the improvement of thermal stability for modified AVImCl/PVDF electrolyte films. When the dose was 60 kGy, AVImCl/PVDF electrolyte films exhibited appropriate ionic conductivity and excellent mechanical performance accompanied by tensile strength of 23.9 MPa and elongation at break of 622%.

Key words: Ionic liquid, Poly (vinylidene fluoride), Radiation modification, Electrolyte film

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  • TL13
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